The Influence of Nanomaterials on the Permanent Deformation of Hot Mix Asphalt
Received: 19 May 2025 | Revised: 8 June 2025 | Accepted: 15 June 2025 | Online: 2 August 2025
Corresponding author: Amjad H. Albayati
Abstract
Improving the permanent deformation resistance of asphalt pavements is a vital challenge. Nanomaterials have emerged as promising additives due to their ability to enhance the binder stiffness and elasticity. This study evaluated the influence of five nanomaterials, namely Nano-Silica (NS), Nano-Alumina (NA), Nano-Zinc (NZ), Nano-Titanium (NT), and Carbon Nanotubes (CNTs) incorporated into a base asphalt binder at varying dosages, with up to 10% for NS, NA, and NT, and up to 5% for NZ and CNT. Fifteen modified binders were assessed using the Multiple Stress Creep Recovery (MSCR) test to obtain non-recoverable creep compliance (Jnr), while the corresponding hot mix asphalt samples underwent repeated load testing and rut depth prediction using the VESYS 5 W model. The results showed that most nanomaterials improved the high-temperature binder properties with a reduced rutting potential. Strong correlations were observed between Jnr and the mixture performance for NS and NZ, whereas NA and CNTs enhanced the mixture stiffness and deformation resistance beyond what was indicated by Jnr alone. NT showed minimal correlation between the binder and mixture performance. While Jnr is a valuable parameter for rutting prediction, it may not always accurately reflect the nano-modified mixture performance, particularly when using higher modification dosages. Therefore, combining the binder with mixture tests provides a reliable performance prediction and optimal nanomaterial selection.
Keywords:
asphalt, nanomaterials, MSCR, permanent deformation, VESYSDownloads
References
S. S. Almasoudi and A. H. K. Albayati, "Statistical Analysis of Component Deviation from Job Mix Formula in Hot Mix Asphalt," Engineering, Technology & Applied Science Research, vol. 12, no. 5, pp. 9295–9301, Oct. 2022. DOI: https://doi.org/10.48084/etasr.5225
AASHTO Guide for Design of Pavement Structures 1993: v.1. Washington, D.C.: AASHTO, 1993.
Y. Huang, Pavement Analysis and Design, 2nd ed. Upper Saddle River, NJ: Pearson, 2004.
Technical Brief: The Multiple Stress Creep Recovery (MSCR) Test. U.S. Depatement of Transportation. Federal Highway Administration, 2011.
H. Paktin, M. Kumar, V. Vinayaka Ram, and S. S. Kar, "Functional and rheological investigations on hydrophilic nanoclay blended bitumen," Discover Sustainability, vol. 5, no. 1, Oct. 2024, Art. no. 337. DOI: https://doi.org/10.1007/s43621-024-00565-z
F. Xiao, J. Wang, J. Yuan, Z. Liu, and D. Ma, "Fatigue and Rutting Performance of Airfield SBS-Modified Binders Containing High Modulus and Antirutting Additives," Journal of Materials in Civil Engineering, vol. 32, no. 3, Mar. 2020, Art. no. 04019366. DOI: https://doi.org/10.1061/(ASCE)MT.1943-5533.0002985
J. D’Angelo, R. Kluttz, R. N. Dongre, K. Stephens, and L. Zanzotto, "Revision of the Superpave High Temperature Binder Specification: The Multiple Stress Creep Recovery Test (With Discussion)," in Journal of the Association of Asphalt Paving Technologists, San Antonio TX, United States, 2007, vol. 76, pp. 123–162.
A. H. Abed and H. Al-Mosawe, "Multiple Stress Creep Recovery Analysis for Iraqi Modified Asphalt Binder," International Journal of Civil Engineering and Technology, vol. 9, no. 11, pp. 3043–3049, Nov. 2018.
Z. K. Taher and M. Q. Ismael, "Moisture Susceptibility of Hot Mix Asphalt Mixtures Modified by Nano Silica and Subjected to Aging Process," Journal of Engineering, vol. 29, no. 04, pp. 128–143, Apr. 2023. DOI: https://doi.org/10.31026/j.eng.2023.04.09
H. A. Rondón-Quintana, J. C. Ruge-Cárdenas, and C. A. Zafra-Mejía, "The Use of Zinc Oxide in Asphalts: Review," Sustainability, vol. 15, no. 14, Jan. 2023, Art. no. 11070. DOI: https://doi.org/10.3390/su151411070
A. M. Mohammed and A. H. Abed, "Effect of nano-TiO2 on physical and rheological properties of asphalt cement," Open Engineering, vol. 14, no. 1, Jan. 2024, Art. no. 20220520. DOI: https://doi.org/10.1515/eng-2022-0520
R. Buhari, M. E. Abdullah, M. K. Ahmad, A. L. Chong, R. Haini, and S. K. A. Bakar, "Physical and rheological properties of Titanium Dioxide modified asphalt," E3S Web of Conferences, vol. 34, 2018, Art. no. 01035. DOI: https://doi.org/10.1051/e3sconf/20183401035
H. Taherkhani, S. Afroozi, and S. Javanmard, "Comparative Study of the Effects of Nanosilica and Zyco-Soil Nanomaterials on the Properties of Asphalt Concrete," Journal of Materials in Civil Engineering, vol. 29, no. 8, Aug. 2017, Art. no. 04017054. DOI: https://doi.org/10.1061/(ASCE)MT.1943-5533.0001889
G. A. Shafabakhsh, M. Sadeghnejad, B. Ahoor, and E. Taheri, "Laboratory experiment on the effect of nano SiO2 and TiO2 on short and long-term aging behavior of bitumen," Construction and Building Materials, vol. 237, Mar. 2020, Art. no. 117640. DOI: https://doi.org/10.1016/j.conbuildmat.2019.117640
N. S. Mashaan, "Rutting Performance of Nano-Silica-Modified C320 Bitumen," Eng, vol. 3, no. 4, pp. 635–645, Dec. 2022. DOI: https://doi.org/10.3390/eng3040043
F. S. Hassan and M. Q. Ismael, "Marshall Properties and Rutting Resistance for Asphaltic Mixtures Modified by Nano-Montmorillonite," Journal of Engineering, vol. 31, no. 2, pp. 19–33, Feb. 2025. DOI: https://doi.org/10.31026/j.eng.2025.02.02
M. Q. Ismael, M. Y. Fattah, and A. F. Jasim, "Improving the rutting resistance of asphalt pavement modified with the carbon nanotubes additive," Ain Shams Engineering Journal, vol. 12, no. 4, pp. 3619–3627, Dec. 2021. DOI: https://doi.org/10.1016/j.asej.2021.02.038
K. Debbarma, B. Debnath, and P. P. Sarkar, "A comprehensive review on the usage of nanomaterials in asphalt mixes," Construction and Building Materials, vol. 361, Dec. 2022, Art. no. 129634. DOI: https://doi.org/10.1016/j.conbuildmat.2022.129634
K. Tabatabaei and F. Tabatabaei, "Assessment of Nanomaterials Use in Asphalt," International Journal of Constructive Research in Civil Engineering, vol. 5, no. 4, pp. 6–12, 2019. DOI: https://doi.org/10.20431/2454-8693.0504002
W. J. Kenis, "Predictive design procedures, VESYS users manual : an interim design method for flexible pavements using the VESYS structural subsystem," FHWA-RD-77-154, Jan. 1978.
H. M. A. A. Kareem and A. H. K. Albayati, "The Possibility of Minimizing Rutting Distress in Asphalt Concrete Wearing Course," Engineering, Technology & Applied Science Research, vol. 12, no. 1, pp. 8063–8074, Feb. 2022. DOI: https://doi.org/10.48084/etasr.4669
F. Alzaidy and A. H. K. Albayati, "A Comparison between Static and Repeated Load Test to Predict Asphalt Concrete Rut Depth," Engineering, Technology & Applied Science Research, vol. 11, no. 4, pp. 7363–7369, Aug. 2021. DOI: https://doi.org/10.48084/etasr.4236
AASHTO T 49 : Standard Test Method for Penetration of Bituminous Materials. Washington, D.C.: AASHTO, 2017.
ASTM D1754/D1754M-09: Standard Test Method for Effect of Heat and Air on Asphaltic Materials (Thin-Film Oven Test). West Conshohocken, PA, USA: ASTM International, 2009.
ASTM D70-17: Standard Test Method for Density of Semi-Solid Bituminous Materials (Pycnometer Method). West Conshohocken, PA, USA: ASTM International, 2017.
AASHTO T 51: Standard Test Method for Ductility of Bituminous Materials. Washington, D.C.: AASHTO, 2018.
AASHTO T 48: Standard Method of Test for Flash Point of Asphalt Binder by Cleveland Open Cup. Washington, D.C.: AASHTO, 2021.
AASHTO T 53: Standard Method of Test for Softening Point of Bitumen (Ring-and-Ball Apparatus). Washington, D.C.: AASHTO, 2022.
ASTM D3515: Standard Specification for Hot-Mixed, Hot-Laid Bituminous Paving Mixtures. West Conshohocken, PA, USA: ASTM International, 2001.
AASHTO T 316: Standard Method of Test for Viscosity Determination of Asphalt Binder Using Rotational Viscometer. West Conshohocken, PA, USA: AASHTO, 2022.
AASHTO T 350: Standard Method of Test for Multiple Stress Creep Recovery (MSCR) Test of Asphalt Binder Using a Dynamic Shear Rheometer. Washington, D.C.: AASHTO, 2023.
G. Derringer and R. and Suich, "Simultaneous Optimization of Several Response Variables," Journal of Quality Technology, vol. 12, no. 4, pp. 214–219, Oct. 1980. DOI: https://doi.org/10.1080/00224065.1980.11980968
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