Influence of γ-Irradiation on the Structural Properties of Indium Monoselenide Crystals

Authors

  • F. A. Al-Mufadi College of Engineering, Qassim University, Saudi Arabia
  • A. El-Taher Physics Dept, Faculty of Science, Al-Azher University, Assuit Branch, Egypt
  • G. A. Gamal Physics Dept, South Valley University, Egypt and College of Engineering, Alqassim University, Saudi Arabia
Volume: 6 | Issue: 6 | Pages: 1264-1268 | December 2016 | https://doi.org/10.48084/etasr.703

Abstract

Indium monoselenide (InSe) which is a layered semiconductor whose energy gap is 1.24 eV has received attention because of its potential applications in optoelectronic devices. In the present work n-type InSe crystals were grown by a special modification of the vertical Bridgman technique. X-ray Diffraction (XRD) patterns showed that all samples were single phased InSe. The crystals were irradiated with 100 - 500 KGy to reveal the influence of irradiation on the structural properties of the samples. Detailed structural analysis was done by Scherrerr’s procedures, x-ray peak broadening and Williamson–Hall plot methods to evaluate the crystalline sizes and lattice strain. Also from the relations between the irradiation dose and the deformation of the lattice parameters we could investigate and discuss the mutation of the dislocation density, grain size, microstrain and crystallinity of the grown crystals. Striking results are found due to irradiation in the present study for the first time.

Keywords:

Crystallite Size, Dislocation, InSe Crystals, Micro strain, Radiation Effects, XRD Analysis

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References

T. Iishii, “High quality single crystal growth of layered InSe semiconductor by Bridgman technique”, Journal of Crystal Growth, Vol 89, pp. 459-462, 1988 DOI: https://doi.org/10.1016/0022-0248(88)90206-0

R. Triboulet, C. Levy-Clement, B. Theys, “Growth of InSe single crystals by the travelling heater method”, Journal of Crystal Growth,Vol. 79, pp. 984-989, 1986 DOI: https://doi.org/10.1016/0022-0248(86)90583-X

A. Segura, F. Pomer, A. Cantarero, “Electron scattering mechanisms in n-type indium selenide”, Phys. Rev., Vol. B29,pp. 5708, 1984 DOI: https://doi.org/10.1103/PhysRevB.29.5708

S. Shigetomi, H. Ohkubo, “Annealing behaviour of optical properties and structure of r.f-sputteredinse films”, Thin Solid Films, Vol. 199, pp. 215 -222, 1991 DOI: https://doi.org/10.1016/0040-6090(91)90003-G

J. Hossain, M. D. Julkarnain, K. S. Sharif, K. A. Khan, “Preparation and Properties of Indium Selenide (InSe) Thin Films for Selective Surface Applications”, Journal of Physical Science and Application, Vol.1, pp. 37-43, 2011.

A. A. Darwish, M. M. El-Nahass, M. H. Bahlol, “Structural and electrical studies on nanostructured InSe Thin films”, Applied Surface Science,Vol. 276, pp. 210–216, 2013 DOI: https://doi.org/10.1016/j.apsusc.2013.03.068

A. Cttevy, A. Kuhn, M. S. Marlin, “Large InSe monocrystals grown from a non-stoichiometric melt”, Journal of Crystal Growth, Vol. 38 pp. 118-122, 1977 DOI: https://doi.org/10.1016/0022-0248(77)90381-5

S. Hirohata, J. S. Moodera, G. P. Berera, “Structural and electrical properties of InSe polycrystalline films and diode fabrication”, Thin Solid Films, Vol. 510, pp. 247–250, 2006 DOI: https://doi.org/10.1016/j.tsf.2005.12.202

C. D. E. Blasi, G. Hicocci, S. Mongelli A.Tepore, F. Zuanni, “Growth and characterization of high quality inse single crystals”, Materials Chemistry and Physics, Vol. 9, pp. 55-64, 1983 DOI: https://doi.org/10.1016/0254-0584(82)90007-4

S. Vives, E. Gaffet, C. Meunier, “X-ray diffraction line profile analysis of iron ball milled powders”, Materials Science and Engineering, Vol. 66, No. A3, pp . 229–238, 2004 DOI: https://doi.org/10.1016/S0921-5093(03)00572-0

V. D. Mote, Y. Purushotham, B. N. Dole , “Williamson-Hall analysis in estimation of latticestrain in nanometer-sized ZnO particles”, Journal of Theoretical and Applied Physics, Vol. 6, pp. 1-8 , 2012

G. A. Gamal, M. Abou Zied, A. A. Ebnalwaled, “The Electronic Properties of the Red P- type Tl2S5 Single Crystals”, Chinese Physics Letters,Vol. 22, pp. 6, 2005 DOI: https://doi.org/10.1088/0256-307X/22/6/064

K. Cenzual, L. M. Gelalo, E. Parthe “Inorganic structure types with revised space group”, Acta Cryst., Vol. B47, pp. 433-439, 1991 DOI: https://doi.org/10.1107/S0108768191000903

S. Q. Xiao, A. H. Gleiter, “Nanocrystalline Titanium Aluminide”, Acta Metall. Mater., Vol. 42, pp. 2535- 2545, 1994 DOI: https://doi.org/10.1016/0956-7151(94)90334-4

R. A. Varin, J. Bystrzycki, A. Calka, “Processing and Fabrication of Advanced Materials”, Intermetallics, Vol. 7, pp. 917, 1999 DOI: https://doi.org/10.1016/S0966-9795(99)00004-7

C. Castro Ribeiro, I. Gibson, M. Adolfo Barbosa, “The uptake of titanium ions by hydroxyapatite particles—structural changes and possible mechanisms”, Biomaterials, Vol. 27, No. 1,pp. 749-176, 2006 DOI: https://doi.org/10.1016/j.biomaterials.2005.09.043

C. E. Krill, R. Birringer, “Crystallite size distribution and dislocation structure determined by diffraction profile analysis” Philos. Mag., Vol. 77, pp. 621,1998

P. Scherrer, “Determining the size and the internal structure of colloidal particles by means of X-rays”, Nachr. Ges. Wiss. Göttingen.,Vol. 26, pp. 98, 1918

G. K. Williamson, W. H. Hall, “Cold-Worked Iron and Molybdenum”, Acta Met.,Vol. 1, pp. 22-28, 1953

M. Wilkens, “The determination of density and distribution of dislocations in deformed single crystals from broadened X-ray diffraction profiles”, Physica Status Solidi A, Vol 2, No. 2,pp. 359-370, 1970 DOI: https://doi.org/10.1002/pssa.19700020224

G. A. Gamal, F. A. Al-Mufadi, A. H. Said, “Effect of Iron Additives on the Microstructure of Hydroxyapatite”, Engineering, Technology & Applied Science Research,Vol. 3, No. 6, pp. 532-539, 2013 DOI: https://doi.org/10.48084/etasr.369

V. D. Mote, Y. Purushotham, B. N. Dole, “Williamson-Hall analysis in estimation of latticestrain in nanometer-sized ZnO particles”, Journal of Theoretical and Applied Physics, Vol. 6, pp. 1-8, 2012 DOI: https://doi.org/10.1186/2251-7235-6-6

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How to Cite

[1]
F. A. Al-Mufadi, A. El-Taher, and G. A. Gamal, “Influence of γ-Irradiation on the Structural Properties of Indium Monoselenide Crystals”, Eng. Technol. Appl. Sci. Res., vol. 6, no. 6, pp. 1264–1268, Dec. 2016.

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